Gautier or Walter V of Brienne (c. 1275 – 15 March 1311) was born in Brienne-le-Château, Aube, Champagne, France. He was the son of Hugh de Candie des Brienne, known as Hugh of Brienne, Count of Brienne and Lecce, and Isabella de la Roche, daughter of Guy I of la Roche, Duke of Athens. He was the heir of the Brienne claim to the Kingdom of Jerusalem and of Cyprus, as well as to Taranto and Sicily.
Walter spent his youth as a hostage in Sicily, in the castle of Agosta. On the death of his father Hugh in 1296, Walter inherited the titles of Count of Brienne, Conversano and Lecce. Like his father, he took up arms in the service of Naples, but was captured in an ambush at Gagliano in 1300. He was freed in 1302 with the signing of the Treaty of Caltabellotta. The death of his mother's first cousin, Guy II of la Roche, in 1308 brought him the Duchy of Athens. There he found himself hard pressed by the Despot of Epirus, the Emperor Andronicus II Palaeologus and the Lord of Vlachia. In 1310, he hired the Catalan Company, then ravaging the Byzantine empire, to fight the Greeks encroaching on his territory. After the Company had successfully reduced his enemies, he attempted to expel the Company from Athens with their pay in arrears. The Company refusing this, Walter marched out with a strong force of French knights from Athens, the Morea and Naples and Greek foot from Athens. Walter's army met the Catalans at the Battle of Halmyros on the river Cephissus in Boeotia on 15 March 1311. The Catalans won a devastating victory, killing Walter and almost all of his cavalry, and seizing his Duchy of Athens, excepting only the Lordship of Argos and Nauplia. His son Walter VI of Brienne succeeded him in all his titles; the Catalan Company nominated one of the surviving knights, Roger Deslaur, as their leader and new Duke of Athens by conquest.
In the year 1306 he married Jeanne de Châtillon and had two children:
| Preceded by Hugh |
Count of Brienne 1296–1311 |
Succeeded by Walter VI |
| Preceded by Guy II |
Duke of Athens 1308–1311 |
Succeeded by Roger Deslaur disputed by Walter VI of Brienne |
|
||||||||||||||||||||